SODIUM HYDROXIDE ICSC: 0360
October 2000
Caustic soda
Sodium hydrate
Soda lye
CAS No: 1310-73-2
RTECS No: WB4900000
UN No: 1823
EC No: 011-002-00-6		     NaOH
Molecular mass: 40.0


TYPES OF
HAZARD /
EXPOSURE		 ACUTE HAZARDS / SYMPTOMS      PREVENTION         FIRE FIGHTING   
FIRE Not combustible. Contact with moisture or water may generate sufficient heat to ignite combustible substances.   In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION      
 
EXPOSURE   AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
Inhalation Corrosive. Burning sensation. Sore throat. Cough. Laboured breathing. Shortness of breath. Symptoms may be delayed (see Notes). Local exhaust or breathing protection. Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention.
Skin Corrosive. Redness. Pain. Serious skin burns. Blisters. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
Eyes Corrosive. Redness. Pain. Blurred vision. Severe deep burns. Face shield, or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Corrosive. Burning sensation. Abdominal pain. Shock or collapse. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.


SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into suitable containers. Wash away remainder with plenty of water. (Extra personal protection: complete protective clothing including self-contained breathing apparatus). C Symbol
R: 35
S: (1/2-)26-37/39-45
UN Hazard Class: 8
UN Pack Group: II

Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.


EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-121
NFPA Code: H 3; F 0; R 1		 Separated from strong acids, metals, food and feedstuffs. Dry. Well closed. Store in an area having corrosion resistant concrete floor.


IMPORTANT DATA
Physical State; Appearance
WHITE, DELIQUESCENT SOLID IN VARIOUS FORMS, WITH NO ODOUR.

Chemical dangers
The substance is a strong base, it reacts violently with acid and is corrosive in moist air to metals like zinc, aluminium, tin and lead forming a combustible/explosive gas (hydrogen - see ICSC 0001). Reacts with ammonium salts
to produce ammonia, causing fire hazard. Attacks some forms of plastics, rubber or coatings. Rapidly absorbs carbon dioxide and water from air. Contact with moisture or water may generate heat (see Notes).

Occupational exposure limits
TLV: 2 mg/m³ (ceiling values) (ACGIH 2000). MAK not established.

 Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

Effects of short-term exposure
Corrosive. The substance is very corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion. Inhalation of an aerosol of the substance may cause lung oedema (see Notes).

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 1390°C
Melting point: 318°C
Density: 2.1 g/cm³
Solubility in water, g/100 ml at 20°C: 109		 This substance may be hazardous to the environment; special attention should be given to water organisms.


NOTES
The applying occupational exposure limit value should not be exceeded during any part of the working exposure.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.
Other UN number: UN1824 Sodium hydroxide solution, Hazard class 8.